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Catalytic cycle
From Wikipedia, the free encyclopedia
A catalytic cycle in chemistry is a term for a multistep reaction mechanism that involves a catalyst . The catalytic cycle is the main method for describing the role of catalysts in biochemistry, organometallic chemistry, materials science, etc. Often such cycles show the conversion of a precatalyst to the catalyst. Since catalysts are regenerated, catalytic cycles are usually written as a sequence of chemical reactions in the form of a loop. In such loops, the initial step entails binding of one or more reactants by the catalyst, and the final step is the release of the product and regeneration of the catalyst. Articles on the Monsanto process, the Wacker process, and the Heck reaction show catalytic cycles.
Often a so-called sacrificial catalyst is also part of the reaction system with the intent purpose of regenerating the true catalyst in each cycle. As the name implies, the sacrificial catalyst is not regenerated and irreversibly consumed. This sacrificial compound is also known as a stoichiometric catalyst when added in stoichiometric quantities compared to the main reactant. Usually the true catalyst is an expensive and complex molecule and added in quantities as small as possible. The stoichiometric catalyst on the other hand should be cheap and abundant.[citation needed]