From Wikipedia, the free encyclopedia

A piece of obsidian, a natural glass

Glass is a type of non-crystalline or amorphous solid. By traditional convention the term glass is reserved for an amorphous solid which has been formed by quenching a glass forming liquid (or melt) through its glass transition temperature sufficiently fast that a regular crystal lattice cannot form.^[1][2][3][4] However, amorphous solids may be formed by methods other than melt quenching, such as ion implantation or the sol-gel method, and since they exhibit the same disordered atomic structure the terms amorphous solid, glass and non-crystalline solid are often regarded as synonyms.

Glass in the common sense contains silica as the main component (glass former), but silica-free glasses also exist.^[5]

The physical and in particular the optical properties of glass make it suitable for technological applications such as windows, containers (bottles, jars, bowls), optics, optoelectronics and laboratory equipment. The ease of formability, and its aesthetic features, such as transparency and pigmentation, render glass a common art medium.

A vase being created at the Reijmyre glassworks, Sweden

The most obvious characteristic of ordinary glass is that it is transparent to visible light, hence its wide application in everyday use. This transparency is due to an absence of electronic transition states in the range of visible light. The homogeneity of the glass on length scales greater than the wavelength of visible light also contributes to its transparency as heterogeneities would cause light to be scattered, breaking up any coherent image transmission. Many household objects are made of glass. Drinking glasses, bowls and bottles are often made of glass, as are light bulbs, mirrors, cathode ray tubes, and windows. Volcanic glasses, such as obsidian, have long been used to make stone tools, and flint knapping techniques can easily be adapted to mass-produced glass.

In research laboratories, flasks, test tubes, lenses and other laboratory equipment are often made of borosilicate glass (such as Pyrex) for its strength and low coefficient of thermal expansion, giving greater resistance to thermal shock and greater accuracy in measurements. For the most demanding applications, quartz glass is used, although it is very difficult to work. Most such glass is mass-produced using various industrial processes, but most large laboratories need so much custom glassware that they keep a glassblower on staff.

Glass is sometimes created naturally from volcanic lava and lightning strikes (Lechatelierite). If the lava is felsic this glass is called obsidian, and is usually black with impurities. Obsidian is a raw material for flintknappers, who have used it to make extremely sharp glass knives since the stone age.

Man-made glass occurrences in nature include trinitite (from nuclear testing), and beach glass.

Main articles: Architectural Glass, Glazing in architecture, and Window

Glass is commonly used in buildings as transparent windows, internal glazed partitions, and as architectural features. It is also possible to use glass as a structural material, for example, in beams and columns, as well as in the form of "fins" for wind reinforcement, which are visible in many glass frontages like large shop windows. Safe load capacity is, however, limited; although glass has a high theoretical yield stress, it is very susceptible to brittle (sudden) failure, and has a tendency to shatter upon localized impact. This particularly limits its use in columns, as there is a risk of vehicles or other heavy objects colliding with and shattering the structural element. One well-known example of a structure made entirely from glass is the northern entrance to Buchanan Street subway station in Glasgow.

Glass in buildings can be of a safety type, including wired, heat strengthened (tempered) and laminated glass. Glass fibre insulation is common in roofs and walls. Foamed glass, made from waste glass, can be used as lightweight, closed-cell insulation. As insulation, glass (e.g., fiberglass) is also used. In the form of long, fluffy-looking sheets, it is commonly found in homes. Fiberglass insulation is used particularly in attics, and is given an R-rating, denoting the insulating ability.

The types and uses of glass for scientific and technical purposes are myriad, and range from applications such as DNA microarrays to large sized neodymium doped glass lasers and glass fibres

Pure SiO₂ glass (the same chemical compound as quartz, or, in its polycrystalline form, sand) does not absorb UV light and is used for applications that require transparency in this region. Large natural single crystals of quartz are pure silicon dioxide, and upon crushing are used for high quality specialty glasses. Synthetic amorphous silica, an almost 100 % pure form of quartz, is the raw material for the most expensive specialty glasses. This type of glass can be made so pure that when combined with Germanium Oxide glass hundreds of kilometers of fibre optic cables can be manufactured which are transparent at infrared wavelengths. Individual fibres are given an equally transparent core of SiO₂/GeO₂ glass, which has only slightly different optical properties (the germanium contributing to a higher index of refraction). Undersea cables have sections doped with erbium, which amplify transmitted signals by laser emission from within the glass itself. Amorphous SiO₂ is also used as a dielectric material in integrated circuits due to the smooth and electrically neutral interface it forms with silicon.

Glasses used for making optical devices are categorized using a six-digit glass code, or alternatively a letter-number code from the Schott Glass catalogue. For example, BK7 is a low-dispersion borosilicate crown glass, and SF10 is a high-dispersion dense flint glass. The glasses are arranged by composition, refractive index, and Abbe number.

Glass polymerization is a technique that can be used to incorporate additives that modify the properties of glass that would otherwise be destroyed during high temperature preparation. Sol gel is an example of glass polymerization and enables the possibility of embedding active molecules, such as enzymes, to add a new level of functionality to glass vessels.

See main articles Glass production, Float glass, Cylinder blown sheet

The following table lists common viscosity fixpoints, applicable to large-scale glass production and experimental glass melting in the laboratory:^[5]

Glass melting technology has passed through several stages:^[7]

• Glass was manufactured in open pits, ca. 3000 B.C. until the invention of the blowpipe in ca. 250 B.C.

• The mobile wood-fired melting pot furnace was used until around the 17th century by traveling glass manufacturers.

• Around 1688, a process for casting glass was developed, which led to glass becoming a much more commonly used material.^{[citation needed]}

• The local pot furnace, fired by wood and coal was used between 1600 and 1850.

• The cylinder method of creating flat glass was used in the United States of America for the first time in the 1820s. It was used to commercially produce windows.^{[citation needed]}

• The invention of the glass pressing machine in 1827 allowed the mass production of inexpensive glass products.^{[citation needed]}

• The gas-heated melting pot and tank furnaces dating from 1860, followed by the electric furnace of 1910.

• Hand-blown sheet glass was replaced in the 20th century by rolled plate glass.^{[citation needed]}

• The float glass process was invented in the 1950s.

Quartz sand (silica) as main raw material for commercial glass production

Pure silica (SiO₂) has a "glass melting point" (at a viscosity η = 100 Poise) of over 2,300°C (4,172°F). While pure silica can be made into glass for special applications (see fused quartz), other substances are added to common glass to simplify processing. One is sodium carbonate (Na₂CO₃), which lowers the melting point to about 1,500°C (2,732°F) in soda-lime glass; "soda" refers to the original source of sodium carbonate in the soda ash obtained from certain plants. However, the soda makes the glass water soluble, which is usually undesirable, so lime (calcium oxide (CaO), generally obtained from limestone), some magnesium oxide (MgO) and aluminum oxide are added to provide for a better chemical durability. The resulting glass contains about 70 to 74 percent silica by weight and is called a soda-lime glass.^[7] Soda-lime glasses account for about 90 percent of manufactured glass.

As well as soda and lime, most common glass has other ingredients added to change its properties. Lead glass, such as lead crystal or flint glass, is more 'brilliant' because the increased refractive index causes noticeably more "sparkles", while boron may be added to change the thermal and electrical properties, as in Pyrex. Adding barium also increases the refractive index. Thorium oxide gives glass a high refractive index and low dispersion, and was formerly used in producing high-quality lenses, but due to its radioactivity has been replaced by lanthanum oxide in modern glasses. Large amounts of iron are used in glass that absorbs infrared energy, such as heat absorbing filters for movie projectors, while cerium(IV) oxide can be used for glass that absorbs UV wavelengths (biologically damaging ionizing radiation).

Besides the chemicals mentioned, in some furnaces recycled glass ("cullet") is added, originating from the same factory or other sources. Cullet leads to savings not only in the raw materials, but also in the energy consumption of the glass furnace. However, impurities in the cullet may lead to product and equipment failure. Fining agents such as sodium sulfate, sodium chloride, or antimony oxide are added to reduce to bubble content in the glass.^[7]

A further raw material used in the production of soda-lime and fiber glass is calumite, which is a glassy granular by-product of the iron making industry, containing mainly silica, calcium oxide, alumina, magnesium oxide (and traces of iron oxide).^[8]

For obtaining the desired glass composition, the correct raw material mixture (batch) must be determined by glass batch calculation.

Properties such as density and melting point vary greatly depending on the material added to the silica: density can range from light display glass with 2.37 g/cm³ to high lead-content flint glass with 7.2 g/cm³, while melting points can range from 500 to 1650°C.^[9] These ranges can be exceeded, but usually at the cost of stability or practicality.

Flat glass for windows and similar applications is produced by the float glass process, where the molten glass floats on top of the perfectly flat molten tin, thus giving it the name "float glass".

Container glass for common bottles and jars is produced by blowing and pressing methods.

Another process used in glass production is marvering. Marvering is the process of rolling hot glass on a metal surface to add a skin of cool semi-solid glass that allows control over the rate at which a bubble within the glass expands.

Besides common silica-based glasses many other inorganic and organic materials may also form glasses, including plastics, carbon, metals, carbon dioxide (see below), phosphates, borates, chalcogenides, fluorides, germanates (glasses based on GeO₂), tellurites (glasses based on TeO₂), antimonates (glasses based on Sb₂O₃), arsenates (glasses based on As₂O₃), titanates (glasses based on TiO₂), tantalates (glasses based on Ta₂O₅), nitrates, carbonates and many other substances.^[5]

Some glasses that do not include silica as a major constituent may have physico-chemical properties useful for their application in fibre optics and other specialized technical applications. These include fluorozirconate, fluoroaluminate, aluminosilicate, phosphate and chalcogenide glasses.

Under extremes of pressure and temperature solids may exhibit large structural and physical changes which can lead to polyamorphic phase transitions.^[10] In 2006 Italian scientists created an amorphous phase of carbon dioxide using extreme pressure. The substance was named amorphous carbonia(a-CO₂) and exhibits an atomic structure resembling that of Silica.^[11]

The amorphous structure of glassy Silica (SiO₂). No long range order is present, however there is local ordering with respect to the tetrahedral arrangement of Oxygen (O) atoms around the Silicon (Si) atoms.

The standard definition of a glass (or vitreous solid) requires the solid phase to be formed by rapid melt quenching.^[1][2][3] Glass is therefore formed via a supercooled liquid and cooled sufficiently rapidly (relative to the characteristic crystallisation time) from its molten state through its glass transition temperature, T_g, that the supercooled disordered atomic configuration at T_g, is frozen into the solid state. Generally, the structure of a glass exists in a metastable state with respect to its crystalline form, although in certain circumstances, for example in atactic polymers, there is no crystalline analogue of the amorphous phase ^[12]. By definition as an amorphous solid, the atomic structure of a glass lacks any long range translational periodicity. However, by virtue of the local chemical bonding constraints glasses do possess a high degree of short-range order with respect to local atomic polyhedra^[13]. It is deemed that the bonding structure of glasses although disordered has the same symmetry signature (Hausdorff-Besicovitch dimensionality) as for crystalline materials^[14].

Glass is generally treated as an amorphous solid rather than a liquid, though different views can be justified since characterizing glass as either 'solid' or 'liquid' is not an entirely straightforward matter.^[15] However, the notion that glass flows to an appreciable extent over extended periods of time is not supported by empirical research or theoretical analysis (see viscosity of amorphous materials). From a more commonsense point of view, glass should be considered a solid since it is rigid according to everyday experience. ^[16]

Some people believe glass is a liquid due to its lack of a first-order phase transition ^[15][17] where certain thermodynamic variables such as volume, entropy and enthalpy are continuous through the glass transition temperature. However, the glass transition temperature may be described as analogous to a second-order phase transition where the intensive thermodynamic variables such as the thermal expansivity and heat capacity are discontinuous. Despite this, thermodynamic phase transition theory does not entirely hold for glass and hence the glass transition cannot be classed as a genuine thermodynamic phase transition. ^[3]

Although the atomic structure of glass shares characteristics of the structure in a supercooled liquid, glass is generally classed as solid below its glass transition temperature.^[18] There is also the problem that a supercooled liquid is still a liquid and not a solid but it is below the freezing point of the material and will crystallize almost instantly if a crystal is added as a core. The change in heat capacity at a glass transition and a melting transition of comparable materials are typically of the same order of magnitude indicating that the change in active degrees of freedom is comparable as well. Both in a glass and in a crystal it is mostly only the vibrational degrees of freedom that remain active, whereas rotational and translational motion becomes impossible explaining why glasses and crystalline materials are hard.

The observation that old windows are often thicker at the bottom than at the top is often offered as supporting evidence for the view that glass flows over a matter of centuries. It is then assumed that the glass was once uniform, but has flowed to its new shape, which is a property of liquid. The likely source of this unfounded belief is that when panes of glass were commonly made by glassblowers, the technique used was to spin molten glass so as to create a round, mostly flat and even plate (the Crown glass process, described above). This plate was then cut to fit a window. The pieces were not, however, absolutely flat; the edges of the disk would be thicker because of centripetal force relaxation. When actually installed in a window frame, the glass would be placed thicker side down for the sake of stability and visual sparkle.^[19] Occasionally such glass has been found thinner side down or on either side of the windows edge, as would be caused by carelessness at the time of installation.

Mass production of glass window panes in the early twentieth century caused a similar effect. In glass factories, molten glass was poured onto a large cooling table and allowed to spread. The resulting glass is thicker at the location of the pour, located at the center of the large sheet. These sheets were cut into smaller window panes with nonuniform thickness. Modern glass intended for windows is produced as float glass and is very uniform in thickness.

Several other points exemplify the misconception of the 'cathedral glass' theory:

• Writing in the American Journal of Physics,^[20] physicist Edgar D. Zanotto states "...the predicted relaxation time for GeO₂ at room temperature is 10³² years. Hence, the relaxation period (characteristic flow time) of cathedral glasses would be even longer".
• If medieval glass has flowed perceptibly, then ancient Roman and Egyptian objects should have flowed proportionately more — but this is not observed. Similarly, prehistoric obsidian blades should have lost their edge; this is not observed either (although obsidian may have a different viscosity from window glass).^[15]
• If glass flows at a rate that allows changes to be seen with the naked eye after centuries, then the effect should be noticeable in antique telescopes. Any slight deformation in the antique telescopic lenses would lead to a dramatic decrease in optical performance, a phenomenon that is not observed.^[15]

Some glasses have a glass transition temperature close to or below room temperature. The behaviour of a material that has a glass transition close to room temperature depends upon the timescale during which the material is manipulated. If the material is hit it may break like a solid glass, however if the material is left on a table for a week it may flow like a liquid. This simply means that for the fast timescale its transition temperature is above room temperature, but for the slow one it is below. The shift in temperature with timescale is not very large however as indicated by the transition of polypropylene glycol of -72 °C and -71 °C over different timescales. ^[12] To observe window glass flowing as liquid at room temperature we would have to wait a much longer time than the universe exists. Therefore it is safe to consider a glass a solid far enough below its transition temperature: Cathedral glass does not flow because its glass transition temperature is many hundreds of degrees above room temperature. Close to this temperature there are interesting time-dependent properties. One of these is known as aging. Many polymers that we use in daily life such as rubber, polystyrene and polypropylene are in a glassy state but they are not too far below their glass transition temperature. Their mechanical properties may well change over time and this is serious concern when applying these materials in construction.

The following table lists some physical properties of common glasses. Unless otherwise stated, the technical glass compositions and many experimentally determined properties are taken from one large study.^[21] Unless stated otherwise, the properties of fused silica (quartz glass) and germania glass are derived from the SciGlass glass database by forming the arithmetic mean of all the experimental values from different authors (in general more than 10 independent sources for quartz glass and Tg of germanium oxide glass). Those values marked in italic font have been interpolated from sililar glass compositions (see Calculation of glass properties) due to the lack of experimental data.

Common soda-lime float glass appears green in thick sections because of Fe²⁺ impurities.

see main article: Glass colors

Colors in glass may be obtained by addition of coloring ions that are homogeneously distributed and by precipitation of finely dispersed particles (such as in photochromic glasses).^[5] Ordinary soda-lime glass appears colorless to the naked eye when it is thin, although iron(II) oxide (FeO) impurities of up to 0.1 wt%^[21] produce a green tint which can be viewed in thick pieces or with the aid of scientific instruments. Further FeO and Cr₂O₃ additions may be used for the production of green bottles. Sulphur, together with carbon and iron salts, is used to form iron polysulphides and produce amber glass ranging from yellowish to almost black.^[32] Manganese dioxide can be added in small amounts to remove the green tint given by iron(II) oxide.

Naturally occurring glass, such as obsidian, has been used by a number of Stone Age societies across the globe for the production of sharp cutting tools and, due to its limited source areas, was extensively traded. According to Pliny the Elder, Phoenician traders were the first to stumble upon glass manufacturing techniques at the site of the Belus River:^[33]

The tradition is that a merchant ship laden with nitrum being moored at this place, the merchants were preparing their meal on the beach, and not having stones to prop up their pots, they used lumps of nitrum from the ship, which fused and mixed with the sands of the shore, and there flowed streams of a new translucent liquid, and thus was the origin of glass.

This is more a reflection of Roman experience of glass production, however, as sand from this area was used in the production of Roman glass due to its low impurity levels. Archaeological evidence suggests that the first true glass was made in Mesopotamia. ^[34] Due to its preferable environment for preservation, the majority of well-studied early glass is found in Egypt although some of this is likely to have been imported. The earliest known glass objects were beads, accidental by-products of metal working slags or perhaps created during the production of faience, a pre-glass vitreous material made by a process similar to glazing (although true glazing over a ceramic body was not used until many centuries after the production of the first glass).

During the Late Bronze Age in Egypt and Western Asia there was an explosion in glass making technology. Archaeological finds from this period include coloured glass ingots, vessels (often coloured and shaped in imitation of highly prized stone ware) and the ubiquitous beads. Dark blue glass, made by adding cobalt, was extensively used and traded during this period and it is thought that the colour was associated with the concept of eternity.

Core-formed amphoriskos (17 cm / 6.7 in tall) 1st century BC, Cyprus

The core forming method was used to make many of the small glass vessels characteristic of this period. Heated glass rods were drawn to create threads which were wound around a pre-formed lime core adhering to a long metal rod. The glass was continually reheated and turned to fuse the threads together. The rod was subsequently allowed to cool and eventually removed, after which the core material was scraped out. Much early glass production, however, relied on techniques borrowed from stone working. This meant that the glass was ground and carved in a cold state.

By the 15th century BC extensive glass production was occurring in Western Asia and Egypt. It is thought the techniques and recipes required for the initial fusing of glass from raw materials was a closely guarded technological secret reserved for the large palace industries of the time. Glass workers in other areas therefore relied on imports of pre-formed glass, often in the form of cast ingots such as those found on the Ulu Burun ship wreck off the coast of Turkey.

Over the next 1000 years glass making and working continued and spread to parts of southern Europe and beyond. Core-formed vessels and beads were still widely produced, but other techniques came to the fore with experimentation and technological advancements. During the Hellenistic period a number of new techniques of glass production were introduced and glass began to be used to make larger pieces, notably table wares. Techniques developed during this period include 'slumping' viscous (but not fully molten) glass over a mould in order to form a dish and 'millefiori' (meaning 'thousand flowers') technique, where canes of multi-coloured glass were sliced and the slices arranged together and fused into a mould to create a mosaic-like effect. It was also during this period that colourless or decoloured glass began to be prized and methods for achieving this effect were investigated more fully.

During the first century BC glass blowing was discovered on the Syro-Palestinian coast, revolutionising the industry and laying the way for the explosion of glass production that occurred throughout the Roman world.

Roman Cage Cup from the 4th Century A.D.

Roman Glass

During the Roman Empire craftsmen working as non-citizens developed many new techniques for the creation of glass.^[35] Through conquest and trade, the use of glass objects and the techniques used for producing them were spread as far as Scandinavia, the British Isles and China.^[36] This spreading of technology resulted in glass artists congregating in areas such as Alexandria in Egypt where the famous Portland Vase was created, the Rhine Valley where Bohemian glass was developed and to Byzantium where glass designs became very ornate and where processes such as enamelling, staining and gilding were developed. At this time many glass objects, such as seals, windows, pipes, and vases were manufactured. Early examples of window glass found in Karanis, Egypt were translucent and very thick^{[citation needed]}. When the Emperor Constantine moved to Byzantium the use of glass continued, and spread to the Islamic world, the masters of glass-vessel making in the later Middle Ages. However, in Europe, the use of glass declined and many techniques were forgotten. The production of glass did not completely stop; it was used throughout the Anglo-Saxon period in Britain. But it did not become common again in the West until its resurgence in the 7th century.

In the medieval Islamic world, the first clear, colourless, high-purity glasses were produced by Muslim chemists, architects and engineers in the 9th century. Examples include Silica glass and colourless high-purity glass invented by Abbas Ibn Firnas (810-887), who was the first to produce glass from sand and stones.^[37] The Arab poet al-Buhturi (820-897) described the clarity of such glass, "Its colour hides the glass as if it is standing in it without a container."^[38]

Stained glass was also first produced by Muslim architects in Southwest Asia using coloured glass rather than stone. In the 8th century, the Arab chemist Jabir ibn Hayyan (Geber) scientifically described 46 original recipes for producing coloured glass in Kitab al-Durra al-Maknuna (The Book of the Hidden Pearl), in addition to 12 recipes inserted by al-Marrakishi in a later edition of the book.^[39]

The parabolic mirror was first described by Ibn Sahl in his On the Burning Instruments in the 10th century, and later described again in Ibn al-Haytham's On Burning Mirrors and Book of Optics (1021).^[40] By the 11th century, clear glass mirrors were being produced in Islamic Spain. The first glass factories were also built by Muslim craftsmen in the Islamic world. The first glass factories in Christian Europe were later built in the 11th century by Muslim Egyptian craftsmen in Corinth, Greece.^[41]

Glass objects from the 7th and 8th centuries have been found on the island of Torcello near Venice. These form an important link between Roman times and the later importance of that city in the production of the material. Around 1000 AD, an important technical breakthrough was made in Northern Europe when soda glass, produced from white pebbles and burnt vegetation was replaced by glass made from a much more readily available material: potash obtained from wood ashes. From this point on, northern glass differed significantly from that made in the Mediterranean area, where soda remained in common use.^[42]

A 16th-century stained glass window

Until the 12th century, stained glass -- glass to which metallic or other impurities had been added for coloring -- was not widely used.

The 11th century saw the emergence in Germany of new ways of making sheet glass by blowing spheres. The spheres were swung out to form cylinders and then cut while still hot, after which the sheets were flattened. This technique was perfected in 13th century Venice.

The Crown glass process was used up to the mid-1800s. In this process, the glassblower would spin approximately 9 pounds (4 kg) of molten glass at the end of a rod until it flattened into a disk approximately 5 feet (1.5 m) in diameter. The disk would then be cut into panes.

Main article: Murano glass

The center for glassmaking from the 14th century was the island of Murano, which developed many new techniques and became the center of a lucrative export trade in dinnerware, mirrors, and other luxury items. What made Venetian Murano glass significantly different was that the local quartz pebbles were almost pure silica, and were ground into a fine clear sand that was combined with soda ash obtained from the Levant, for which the Venetians held the sole monopoly. The clearest and finest glass is tinted in two ways: firstly, a small or large amount of a natural coloring agent is ground and melted with the glass. Many of these coloring agents still exist today; for a list of coloring agents, see below. Black glass was called obsidianus after obsidian stone. A second method is apparently to produce a black glass which, when held to the light, will show the true color that this glass will give to another glass when used as a dye. ^[43]

The Venetian ability to produce this superior form of glass resulted in a trade advantage over other glass producing lands. Murano’s reputation as a center for glassmaking was born when the Venetian Republic, fearing fire might burn down the city’s mostly wood buildings, ordered glassmakers to move their foundries to Murano in 1291. Murano's glassmakers were soon the island’s most prominent citizens. Glassmakers weren't allowed to leave the Republic, however. Many craftsmen, however, took a risk and set up glass furnaces in surrounding cities and as far afield as England and the Netherlands.

A decorative glass store in Rome

Main article: Glass art

Beginning in the late 20th century, glass started to become highly collectable as art. Works of art in glass can be seen in a variety of museums, including the Chrysler Museum, the Museum of Glass in Tacoma, the Metropolitan Museum of Art, the Toledo Museum of Art, and Corning Museum of Glass, in Corning, NY, which houses the world's largest collection of glass art and history, with more than 45,000 objects in its collection.^[44]

Several of the most common techniques for producing glass art include: blowing, kiln-casting, fusing, slumping, pate-de-verre, flame-working, hot-sculpting and cold-working. Cold work includes traditional stained glass work as well as other methods of shaping glass at room temperature. Glass can also be cut with a diamond saw, or copper wheels embedded with abrasives, and polished to give gleaming facets; the technique used in creating waterford crystal ^[45]. Art is sometimes etched into glass via the use of acid, caustic, or abrasive substances. Traditionally this was done after the glass was blown or cast. In the 1920s a new mould-etch process was invented, in which art was etched directly into the mould, so that each cast piece emerged from the mould with the image already on the surface of the glass. This reduced manufacturing costs and, combined with a wider use of colored glass, led to cheap glassware in the 1930s, which later became known as Depression glass^[46]. As the types of acids used in this process are extremely hazardous, abrasive methods have gained popularity.

Objects made out of glass include not only traditional objects such as vessels (bowls, vases, bottles, and other containers), paperweights, marbles, beads, smoking pipes, bongs, but an endless range of sculpture and installation art as well. Colored glass is often used, though sometimes the glass is painted, innumerable examples exist of the use of stained glass.

The Harvard Museum of Natural History has a collection of extremely detailed models of flowers made of painted glass. These were lampworked by Leopold Blaschka and his son Rudolph, who never revealed the method he used to make them. The Blaschka Glass Flowers are still an inspiration to glassblowers today. ^[47]

• Noel C. Stokes; The Glass and Glazing Handbook; Standards Australia; SAA HB125–1998
• Brugmann, Birte. Glass Beads from Anglo-Saxon Graves: A Study on the Provenance and Chronology of Glass Beads from Anglo-Saxon Graves, Based on Visual Examination. Oxbow Books, 2004. ISBN 1-84217-104-6

Look up glass in Wiktionary, the free dictionary.

Wikimedia Commons has media related to:

Glass

• The Canadian Museum of Civilization - The Story of Glass Making in Canada
• Corning Museum of Glass
• A comprehensive guide to art glass and crystal around the world
• Working Description Furnace & Moleria - Murano Glass
• Informative website about the glass industry
• Substances used in the Making of Colored Glass
• Glass property measurement and calculation
• Almost 400 articles and images about glass (mostly art glass)