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Standard state
From Wikipedia, the free encyclopedia
In chemistry, the standard state of a material is its state at 1 bar (100 kilopascals). This pressure of 1 bar was changed from 1 atm by IUPAC in 1990. The standard state of a material can be defined at any given temperature (most commonly 25 degrees Celsius).
It should be noted that the standard state is an arbitrarily chosen non-zero value, not a natural zero point.
For a given material or substance, the standard state is the reference state for the material's thermodynamic state properties such as enthalpy, entropy, Gibbs free energy, and for many other material standards. The standard enthalpy of formation for an element in its standard state is 0.
When the standard state is referred to in a chemical reaction, it also includes the condition that the concentrations of all solutions are at unity in whatever measure of concentration is specified. If that is molarity that would be 1 moldm-3 and for molality 1 molkg-1. If mole fraction is used the pure liquid or solid is the standard state (x=1). As it is possible (and in principle legitimate) to take a different unit for each of the species in the reaction, the nature of the standard state needs to be specified when reporting or tabulating. Although a definition involving 1 mol/L (molarity at unity) of A in combination with pure B (mole fraction at unity) is clearly a condition that can never be met, such a non-existent standard state nevertheless leads to a consistent system of tabulated values, provided it is used consistently by all. Of course these values are different from those where a different standard state is adopted.
In the time of their development (the 19th century) the Plimsoll - symbol was adopted as a superscript o to indicate the non-zero nature of the chosen reference state. For typographic reasons this symbol is often abridged to a rather misleading zero superscript o in later texts.